K(I)-M(II) (M = Co, Mn) heterometallic-(perfluorinated) organic frameworks containing inorganic layered K–O–M linkages: synthesis, crystal structure, and magnetic properties

K(I)-M(II) (M = Co, Mn) heterometallic-(perfluorinated)organic frame- works containing rare inorganic layered K–O–M linkages: synthesis, crystal structure, and magnetic properties

Octacyanotungstate(v)-based square W(2)M(2) (M = Co, Mn) complexes: synthesis, structure and magnetic properties.

The preparation, single-crystal X-ray crystallography and magnetic properties are reported for two tetranuclear cluster complexes based on [W(V)(CN)(8)](3-) octacyanometallates. Reactions of [W(V)(CN)(8)](3-) with Co(II) ions in the presence of the capping ligand tpm (tpm = tri(1H-pyrazol-1-yl)methane) lead to the formation of complex 1 [(tpm)(2)Co(II)][W(V)(2)(CN)(16)Co(2)(tpm)(2)(H(2)O)(2)].4...

Synthesis, crystal structure and luminescence properties of one inorganic-organic hybrid compound [FTMA]2[Co(NCS)4] (FTMA = ferrocenylmethyltrimethylammonium cation).

A new inorganic-organic hybrid compound [FTMA](2)[Co(NCS)(4)] (FTMA = ferrocenylmethyltrimethylammonium cation) has been synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography. Co(II) atom has a distorted tetrahedral environment with four N atoms of four NCS(-) anions. In the solid state there are C-H⋯π interactions between adjacent ferrocenyl cations, which gener...

Synthesis, structure, and magnetic properties of novel B-site ordered double perovskites, SrLaMReO6 (M = Mg, Mn, Co and Ni).

Four new double perovskites, SrLaMReO(6) (M = Mg, Mn, Co, Ni) in which Re(5+) (5d(2)) is present, were prepared via conventional solid state reactions and characterized by X-ray and neutron powder diffraction, XANES, SQUID magnetometry, and muon spin relaxation (μSR). Synchrotron X-ray and neutron diffraction experiments confirmed that all compounds crystallize in the monoclinic P2(1)/n structu...

Solvothermal synthesis, crystal structure, and properties of lanthanide-organic frameworks based on thiophene-2,5-dicarboxylic acid.

A series of lanthanide-organic framework coordination polymers, {[La(2)(TDC)(2)(NO(3))(H(2)O)(4)](OH)·5H(2)O}(n) (1) and [Ln(TDC)(NO(3))(H(2)O)](n) (TDC = thiophene- 2, 5- dicarboxylic acid; Ln = Nd(2), Sm(3), Eu(4), Gd(5), Tb(6), Dy(7), Ho(8), Er(9), Yb(10)) have been synthesized by solvothermal reaction and characterized by elemental analysis, FT-IR, TG analysis, single-crystal X-ray diffract...